MII(C4H12N2)[B2P3O12(OH)] (MII = Co, Zn): Synthesis and Crystal Structure of Novel Open Framework Borophosphates

2001 ◽  
Vol 627 (1) ◽  
pp. 61-67 ◽  
Author(s):  
Gerd Schäfer ◽  
Horst Borrmann ◽  
Rüdiger Kniep
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure ◽  
Open Framework

The synthesis and crystal structure of a new open-framework zincophosphate UiO‐17

1999 ◽  
Vol 9 (12) ◽  
pp. 3119-3123 ◽  
Author(s):  
Kjell Ove Kongshaug ◽  
Helmer Fjellvåg ◽  
Karl Petter Lillerud
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure ◽  
Open Framework

Synthesis and Crystal Structure of IM-6, a New Open Framework Cobalt–Gallium Phosphate with Ten- and Twelve-Membered Pore Openings

2003 ◽  
Vol 9 (4) ◽  
pp. 856-861 ◽  
Author(s):  
Ludovic Josien ◽  
Angélique Simon-Masseron ◽  
Volker Gramlich ◽  
Joël Patarin ◽  
Loïc Rouleau
Keyword(s):  
Crystal Structure ◽  
Synthesis And Crystal Structure ◽  
Open Framework ◽  
Gallium Phosphate

scholarly journals Synthesis and crystal structure of two new phosphates with Alluaudite type structure: (M, Mn)3Fe(PO4)3 (M= Ca, Cd)

2018 ◽  
Vol 149 ◽  
pp. 01084 ◽  
Author(s):  
Ghaleb Alhakmi ◽  
Abderrazzak Assani ◽  
Mohamed Saadi ◽  
Lahcen El Ammari
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Type Structure ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Open Framework ◽  
Bivalent Cations ◽  
The Common

Two new phosphates with alluaudite type structure (M, Mn)3Fe(PO4)3 (M= Ca, Cd), namely Ca1.54Mn1.46Fe(PO4)3 and Cd0.66Mn2.34Fe(PO4)3, has been synthesized by a solid state reaction and characterized by single-crystal X-ray diffraction. The two compounds crystallize in the monoclinic system with C2/c space group. Their open framework results from (Fe1/Mn1)2O10 units of edge-sharing (Fe/Mn)O6 octahedra, which alternate with M(1)O6 octahedra (M(1)=Ca1/Mn2 or Cd1/Mn2) that form infinite chains running along [10-1] direction. These chains are linked together through the common corners of PO4 tetrahedra giving rise to two types of tunnels occupied by bivalent cations Ca2+ or Cd2+ and Mn2+.

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